Abstract
A novel manganese compound with Fe(IV) building block has been synthesized and characterized by single-crystal diffraction analysis, which presents of a 1D staircase chain structure. The adjacent staircase chains are expended into a 2D layer through π-π interaction between the terminal oxalyl groups. Furthermore, the 2D layers are connected to form a 3D supramolecular framework by rich hydrogen bonds. Low-temperature magnetic measurements reveal that intrachain antiferromagnetic couplings dominates through the FeIV-oxamido-MnII pathways, concomitantly with a typical ferrimagnetic behavior.
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