Abstract

High-fidelity 3D printing of nanoscale objects is an increasing relevant but challenging task. Among the few fabrication techniques, focused electron beam induced deposition (FEBID) has demonstrated its high potential due to its direct-write character, nanoscale capabilities in 3D space and a very high design flexibility. A limitation, however, is the low fabrication speed, which often restricts 3D-FEBID for the fabrication of single objects. In this study, we approach that challenge by reducing the substrate temperatures with a homemade Peltier stage and investigate the effects on Pt based 3D deposits in a temperature range of The findings reveal a volume growth rate boost up to a factor of , while the shape fidelity in 3D space is maintained. From a materials point of view, the internal nanogranular composition is practically unaffected down to , followed by a slight grain size increase for even lower temperatures. The study is complemented by a comprehensive discussion about the growth mechanism for a more general picture. The combined findings demonstrate that FEBID on low substrate temperatures is not only much faster, but practically free of drawbacks during high fidelity 3D nanofabrication.

Highlights

  • Three-dimensional printing of nanoscale objects is an emerging technology on the route to future applications in research and development

  • The removal of carbon contaminants from 3D-focused electron beam induced deposition (FEBID) materials is discussed in detail elsewhere [13,21,22], while we address different strategies to tackle the speed issue

  • We investigate the effects of the substrate temperature (TS ) in a range of

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Summary

Introduction

Three-dimensional printing of nanoscale objects is an emerging technology on the route to future applications in research and development. Among the few additive manufacturing processes that allow resolution in the sub-100 nm scale, 3D nanoprinting via focused electron beam induced deposition (3D-FEBID) has demonstrated great potential This technology uses a nanosized, focused electron beam to locally deposit material from precursor molecules temporarily adsorbed on the substrate from the gas phase. By combining small lateral electron beam displacements (sub-10 nm) and long exposure times (milliseconds), the deposit lifts off from the substrate, resulting in inclined, freestanding nanowires. This 3D-FEBID technique allows 3D printing of even complex structures with nanoscale dimensions [2]

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