Abstract

The kinetics of the hydrogenation of magnesium composites with graphene-like material (GLM) on which nickel particles are deposited (Ni/GLM) and dehydrogenation of MgH2+Ni/GLM composites is studied. The mechanism of the reactions is revealed using the obtained results and the mathematical processing of curves with the Avrami–Erofeev equation. It is found that Ni/GLM considerably accelerates the hydrogenation of Mg and the decomposition of MgH2 in the composite. The hydrogen-accumulating Mg+Ni/GLM composite is shown to have cyclic stability with rapid and virtually complete reversible hydrogenation.

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