Abstract
An exclusively stereoselective reaction of AcOH elimination in the title acetate of cloprostenol was described, which led with high yield under Pd(PPh3)4-NaH-THF catalysis to the corresponding 13E,15Z-derivative. In contrast, under the same conditions, the use of methyl ester of 15-acetate 11-deoxyprostaglandin E1 results in regioisomeric reductive elimination products.
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