Feasibility of Using Cordierite Glass‐Ceramics as Tile Glazes

Abstract

Basic principles of fabricating tile glazes based on cordieritic glass‐ceramics are explained. Glass compositions from the MgO‐Al2O3‐SiO2 three‐component phase diagram have been melted with and without the nucleating agent TiO2. Additionally, a sodium borosilicate glass that is commonly used in the tile glaze industry has been wet milled, together with the previous compositions, to produce a coating slip. Studies are focused on the role of the nucleating agent and glassy formulation in the crystallization of the glass‐ceramic system using differential thermal analysis, X‐ray diffractometry, and scanning electron microscopy. When added to a borosilicate glass, only one composition is capable of crystallizing cordierite under a fast‐firing cycle used for “monoporosa” production. The porosity of the glaze layer is sufficiently low and the crystal size is small to ensure good mechanical and chemical properties. The presence of cordierite crystals in the glaze should enhance abrasion and acid resistance, in comparison to a traditional matte glaze that contains mostly enstatite or diopside crystals.