Feasibility of luminescent multilayer sol-gel thermal barrier coating manufacturing for future applications in through-thickness temperature gradient sensing

Abstract

This paper investigates the feasibility of manufacturing sol-gel multilayer thermal barrier coatings (TBC) functionalized with different lanthanide ions Ln3+ having distinct photo-luminescence emission wavelengths (Ln=Sm, Eu, Dy, Er, Tm) for future applications in temperature gradient sensing. Ln3+ doped 9.75mol% yttria stabilized zirconia (YSZ) powders were produced to study the effect of activator concentration on luminescence intensity and host matrix crystal structure. Self-quenching was found to limit the maximum signal-to-noise ratio achievable with Sm3+, Dy3+, Er3+ and Tm3+ activators, which was not the case for Eu3+ in the 1–10mol% range. The increase in activator was found to affect the crystal structure of YSZ. A solution was proposed that suppressed this effect while significantly increasing the luminescence intensity of all activators. Finally a TBC sensor prototype integrating Eu3+, Er3+ and Dy3+ doped layers distributed throughout the thickness was successfully deposited by a dip-coating sol-gel process and showed promising through-thickness luminescence sensing capabilities.