Abstract
ArF water immersion exposure systems with a numerical aperture (NA) of over 1.3 are currently being developed and are expected to be used for the node up to 45-nm half-pitch. Although there are multiple candidates for the next generation node, we here focus on ArF immersion lithography using high-index materials. The refractive index of highindex fluids is typically about 1.64 and is larger than that of fused silica (~1.56). In this situation, the NA is limited by the refractive index of silica and is at most 1.45. An exposure system with 1.45 NA is not suitable for 32-nm hp node, but may be used for 37-nm hp node. In spite of this limitation, the system has the advantage of slight alterations from the current system using water as immersion fluid. On the other hand, high-index lens material is effective to increase the NA of projection optics further. At present, LuAG, whose refractive index is 2.14, is most promising as high-index lens material. The combination of high-index fluid and high-index lens material can enhance the NA up to about 1.55 and the exposure system would be available for the 32-nm half-pitch node. Although high-index immersion lithography is attractive since it is effective in raising resolution, such new materials should be examined if these materials can be used for high precision projection optics. Here, we have investigated optical characteristics of high-index materials in order to realize high-index immersion systems.
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