Fe3O4@SiO2@SBA-3@CPTMS@Arg-Cu: preparation, characterization, and catalytic performance in the conversion of nitriles to amides and the synthesis of 5-substituted 1H-tetrazoles.

Abstract

A novel, efficient, and recyclable mesoporous Fe3O4@SiO2@SBA-3@CPTMS@Arg-Cu nanocatalyst was synthesized by grafting l-arginine (with the ability to coordinate with Cu) onto a mixed phase of a magnetic mesoporous SBA-3 support. The catalyst was characterized using several techniques, including Fourier-transform infrared (FT-IR) spectroscopy, thermogravimetric analysis (TGA), vibrating sample magnetometry (VSM), X-ray diffraction (XRD) analysis, N2 adsorption-desorption analysis, scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), energy dispersive X-ray (EDX) analysis, and atomic absorption spectroscopy (AAS). The resulting solid material possessed a surface area of 145 m2 g-1 and a total pore volume of 34 cm3 g-1. The prepared mesoporous material was studied as a practical, recyclable, and chemoselective catalyst in some organic functional group transformations such as the conversion of nitriles to amides and synthesis of 5-substituted 1H-tetrazoles. This novel magnetic nanocatalyst proved to be effective and provided the products in high to excellent yields under green solvent conditions. Meanwhile, the as-prepared Fe3O4@SiO2@SBA-3@CPTMS@Arg-Cu demonstrated excellent reusability and stability under reaction conditions, and its catalytic activity shown only a slight decrease after seven consecutive runs. Therefore, the as-synthesized magnetic Fe3O4@SiO2@SBA-3@CPTMS@Arg-Cu has broad prospects for practical applications, and offers various benefits such as simplicity, nontoxicity, low cost, simple work-up, and an environmentally benign nature.