Fe2O3 nanoparticles encapsulated in the inner walls of integrated 3D carbon tube grid as high-performance anode for lithium-ion batteries

Abstract

Ferric oxide (Fe2O3) holds huge potential as a promising anode material for lithium-ion batteries (LIBs) due to its high theoretical capacity and low cost, however, its battery performance is still limited by the intrinsic poor conductivity and huge volume variation during lithiation and de-lithiation processes. Herein, we developed a self-standing 3D interconnected vertical and lateral carbon tube (3D-CT) grid with Fe2O3 nanoparticles (NPs) encapsulated in the wall of CT (denoted as 3D-CT@Fe2O3-NPs@C), as structurally-integrated anode without any inactive components. The 3D-interconnected vertical and lateral CTs with open channels not only provide plenty of attachment sites for the Fe2O3 NPs and accommodate the strain generated by the volume variation of Fe2O3, but also facilitate the fast ions and electrons transfer. Therefore, the self-supported 3D-CT@Fe2O3-NPs@C electrode delivers superior cycling and high-rate performance with a high stable specific capacity of 896.2 mAh g−1 at the current density of 1.0 A g−1 after 700 cycles. Even at the high current density of 4.0 A g−1, a reversible capacity of 488.1 mAh g−1 can be reached based on the mass of the electrode. This study provides a facile and efficient strategy to improve the electrochemical performance of LIBs through the design of structurally-integrated grid electrode.