Fe/N co-doped mesoporous carbon derived from cellulose-based ionic liquid as an efficient heterogeneous catalyst toward nitro aromatic compound reduction reaction

Abstract

Iron and nitrogen-doped carbon substances with abundant active sites that related to dispersion of heteroatom species (Fe and N) on the surface of carbonous structure, are promising choice for eco-friendly catalytic reactions. Herein, cellulose-based ionic liquid (IL) derivative not only employed as the both nitrogen and iron heteroatom precursors, but also has been used as the green and biodegradable substrate. The non-noble Fe-NC@550, was successfully fabricated by convenient carbonization of cellulose-based IL. Further, the FeCl4− anion was used as the iron precursor and also it has been applied to elevate the SSA (specific surface area) of catalyst (from 40.96 to 160.42 m2/g) due to the presence of chlorine. On the basis of several pertinent physicochemical and experimental outcomes, the structure of the catalyst was successfully proved in different synthetic steps. As expected, the Fe-NC@550 exhibited the substantial efficiency toward hydrogenation of nitroarenes with high TOF value and also remarkable reusability.