Abstract

A series of Fe-doped TiO2 trilayer films were prepared successfully by using the ion-implantation technique. The aim of the ion implantation was to enhance charge transfer and to reduce charge recombination. A maximum conversion efficiency of 4.86% was achieved in cells using Fe-ion-implanted electrodes with the illumination of 6 × 10 15 atom∕cm 2 . It is 14.1% higher than that of the cells without ion implantations. The sig- nificant improvement in conversion efficiency by Fe-ion implantation could be contributed to the enhancement of dye uptake and charge transfer, as indicated from the incident photon-to-collected electron conversion efficiency and ultraviolet-visible measurements. Furthermore, the implanted Fe-ions introduce impurity levels in the bandgap of TiO2, and this improves the electron injection efficiency from lowest unoccupied molecular orbital of excited N719 into the conduction band of TiO2. © 2016 Society of Photo-Optical Instrumentation Engineers (SPIE) (DOI: 10.1117/1. OE.55.6.067107)

Full Text
Published version (Free)

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call