Abstract
spectroscopy and resistivity measurements. The in situ Mossbauer spectra, measured at 7 K for the as-prepared films, show that the Fe impurities in the Cd and Zn films mainly occupy lattice sites and have isomer shift values of 0.70 mm/s and 0.53 mm/s, respectively. While for Fe in Zn the isomer shift value agrees well with those in the literature, the value for Fe in Cd is significantly larger than the value previously reported. First-principles calculations of the isomer shift values for Fe impurities on substitutional sites in Zn and Cd, respectively, agree quite well with the experimentally found values.
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