Abstract
We prepared an iron(II) spin crossover complex with a new ligand, [1,2,5]thiadiazolo[3,4-f][1,10]phenanthroline, which is a 1,10-phenanthroline analogue annulated with a thiadiazole moiety. X-Ray crystal analysis indicated a 3D network structure formed by short S⋯S contacts, and magnetic measurements revealed a broad transition above room temperature.
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