Abstract

The enrichment of Fe, relative to alpha elements such as O and Mg, represents a potential means to measure the ages of quasi-stellar object (QSO) host galaxies and probe nucleosynthesis in the early universe. QSOs exhibit prominent Fe ii features and Mg ii 2800 Å resonance doublet emission in the ultraviolet. Although chemical evolutionary models predict that the Fe/Mg abundance ratio decreases with increasing redshift, measurements of QSO Fe ii (UV)/Mg ii emission line ratios show large scatter from 1 to 20, with no redshift dependency up to z∼6.4. Before using Fe ii emission as an abundance indicator, one must ascertain how Fe ii emission varies with physical conditions. We have constructed an 830-level model atom for Fe ii and used it in a photoionization code to calculate Fe ii emission. This model is more sophisticated than previous efforts, and uses the most recent laboratory atomic data and includes the numerous transitions that are sensitive to the strong radiation field in QSOs. Predicted Fe ii(UV)/Mg ii ratios and fluxes strongly depend on non-abundance factors such as microturbulence, ionizing flux, and hydrogen density; all must be taken into account before any accurate abundance can be derived. Our calculations show that Fe ii is the dominant coolant at densities found in active galactic nucleus (AGN) broad emission line regions (BLRs), and must be included in photoionization modelling. Our close collaboration with spectroscopists at Lund University has been highly beneficial for further development of our Fe ii model, most importantly through atomic data studies that link high-energy levels in Fe ii. Additional studies of the atomic structure of Fe ii are necessary to improve our understanding of the AGN continua by accounting for the effects of the Fe ii pseudo-continuum, which blanket QSO spectra from 1000 to 10 000 Å. Predicted Fe ii emission spectra, suitable for BLRs in AGN, are available at http://iacs.cua.edu/people/verner/Feii.

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