Abstract

A variation of iron ionic states in Fe 2p spectra for charged and discharged lithium iron phosphate (LiFePO4) thin film as a cathode corresponds to cathode behavior. The shape of valence band spectra was investigated, and a peak appeared at about 1.6 eV for discharged LiFePO4 thin film. This peak was attributed to the Fe2+ state without oxidation state using oxidized LiFePO4 thin films. The variation of iron ionic states from Fe 2p spectra was confirmed using this peak. Copyright © 2016 John Wiley & Sons, Ltd.

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