Fatigue crack growth behavior of Ti-6Al-6V-2Sn in methanol and methanol-water solutions

Abstract

Differences in the corrosion fatigue crack growth behavior of anα–β titanium alloy in chloride-containing aqueous and methanol environments are reported, and discussed in relation to differences in repassivation behavior for the two types of environments. Experiments have been conducted with various solution mixtures of water (a passive film-forming environment) and methanol (a nonfilm-forming environment) to define the role of repassivation in controlling fracture modes and crack growth rates at different frequencies. The critical event in determining whether the repassivation process can suppress environmental fatigue fracture is the interaction between the rate of exposure of fresh metal surfaces at the crack tip and the rate at which they can be repassivated. The out-come of this mechano-chemical interaction is shown to be dependent on the frequency and stress intensity(ΔK) level as well as the chemistry of the environment. As a result, differences in repassivation behavior for methanol-water solutions can be correlated with major differences in fatigue crack growth rates and fracture modes at low ΔK levels, whereas repassivation differences have little effect at high ΔK levels. Based on these low-ΔK corrosion fatigue characteristics, methanol solutions are concluded to be far more detrimental to titanium alloys than aqueous solutions.