Fate of Lead and Cadmium in Precalciner Cement Plants and Their Atmospheric Releases.

Abstract

Disclosing the fate of lead (Pb) and cadmium (Cd) during the cement production process is the key to control their atmospheric emissions, which have not attracted much attention yet. In this study, three precalciner cement plants (CPs) using different raw materials in Guizhou Province in Southwest China were investigated. It showed that the concentrations of Pb and Cd in different raw materials and the associated total metal input of these materials were different among CPs; the behavior of Pb and Cd were almost the same during the clinker production process that there has been no accumulation of these two elements inside the system, and nearly all input of Pb and Cd were discharged by the clinker. Although the temperature of clinkerization was pretty high of 1450 °C, the atmospheric emission ratio of both metals was negligible (<0.006% for Pb and <0.002% for Cd of the total output, respectively); the main reason might be that the two elements were incorporated into the minerals of clinker, either as silicate or sulfate. The long-term environmental impacts of some high Pb-and Cd-laden clinkers and cement need to be monitored and evaluated.