Fate of emerging contaminants in a sequencing batch reactor and potential of biological activated carbon as tertiary treatment for the removal of persisting contaminants

Abstract

The study aims to understand the occurrence and removal of 20 emerging contaminants (ECs) in each unit process of a sequencing batch reactor-based wastewater treatment plant (WWTP) and explore the potential of biological activated carbon (BAC) for the treatment of residual ECs and organic matter in the secondary effluent. Analgesic-acetaminophen, anti-inflammatory drug-ibuprofen, and stimulant-caffeine were detected at high concentrations in the influent. Most of the removal was observed in the biological treatment stage in the SBR basins. The mass load of the ECs was 2.93 g/d in the secondary effluent and 0.4 g/d in the final sludge, while the total removal of the mass load of ECs till the secondary treatment stage was 93.22%. 12 of the 20 ECs were removed by more than 50%, while carbamazepine (negative removal), sulfamethoxazole, and trimethoprim were removed by less than 20%. As a polishing step and to remove residual ECs, two BAC units were studied for 11,000 bed volumes (324 days). Packed column studies on granular activated carbon were conducted, and GAC development to BAC was monitored. SEM and FTIR were used to confirm and characterize the BAC. The BAC appeared to be more hydrophobic than the GAC. The BAC removed 78.4% and 40% of the dissolved ECs and organic carbon at an optimum EBCT of 25 min. Carbamazepine, sulfamethoxazole, and trimethoprim were removed by 61.5, 84, and 52.2%, respectively. Parallel column tests revealed adsorption as an important mechanism for the removal of positively charged compounds. The results indicate that the BAC is an effective tertiary/polishing technique for removing organic and micropollutants in the secondary wastewater effluent.