Fast traveling waves in the phase-field theory: effective mobility approach versus kinetic energy approach

Abstract

A phase-field model for small and large driving forces on solidification and melting of a pure substance or alloys is formulated. Derivations of the phase-field model are based on the effective mobility approach and on the kinetic energy approach to analyze fast phase transformation from metastable liquid to solid phase. A hodograph equation (an acceleration-velocity dependent equation of the Gibbs–Thomson type) which predicts the non-linear behavior in the velocity of the crystal–liquid interface is found at the large driving force on transformation and analyzed for different thermodynamic potentials. Traveling wave solutions of this equation are found for double-well and double-obstacle potentials. The velocity-dependent traveling waves as a function of driving force on transformation exhibit non-linearity of the solutions. Namely, in the relationship ‘velocity–driving force’ exists a maximum at a fixed undercooling which is very well known in the solidification of glass-forming metals and alloys. The predicted solidification velocity is quantitatively compared with the molecular dynamics simulation data obtained by Tang and Harrowell (2013 Nat. Mater. 12 507–11) for the solidification of congruently melting Cu–Zr binary alloy. The comparison confirms a crucial role of local non-equilibrium such as relaxation of gradient flow in the quantitative description of fast phase transformations.