Fast sinter crystallisation of waste glasses

Abstract

Two glasses, belonging to the CaO–Al2O3–SiO2 system and corresponding to the melting of mixtures of industrial wastes (recycled glasses, mining residues, ashes, asbestos containing cements, etc.), have been successfully converted into dense glass ceramics by sintering with concurrent crystallisation. The usage of fine glass powders (<37 μm) allowed very short sintering treatments, due to the enhanced nucleating activity of glass surfaces. In particular, dense glass ceramics could be produced by direct insertion of pressed glass powders in the furnace at the sintering temperature, followed by rapid cooling at room temperature after a 30 min holding time. The proposed approach evidences the feasibility of sintered glass ceramics by the fast and economic processes employed for traditional ceramics, with the advantage of superior mechanical properties (bending strength exceeding 100 MPa, Vickers' microhardness exceeding 6 GPa). Like in traditional ceramics, clay and water could be used for the shaping of pressed tiles, thus posing the conditions for massive industrial production.