Abstract
Abstract A new bifunctional photorefractive active succinate (TPD-2DCVA) consisting of a tetraphenyldiaminobiphenyl (TPD) unit and 4-dicyanovinylaniline (DCVA) moieties was prepared, which forms stable molecular glass. The glass-transition temperatures (Tg’s) of TPD-2DCVA-based composites were efficiently controlled by the doping of small amount of plasticizers. The compound possesses a high photoconductivity of 2.1 × 10−9 cm Ω−1 W−1 at 50 V µm−1. A gain coefficient of 56.7 cm−1 at electric field of 56 V µm−1 was achieved. Fast response times of 29–37 ms were also obtained at low electric fields for these composites.
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