Abstract
Activationless, solvent-controlled fast intramolecular electron transfer (ET) kinetics are reported for three N-arylaminonaphthalenesulfon-N,N-dimethylamides over a wide temperature range in three pentanediols. A stretched exponential decay (Williams-Watts) using the longitudinal relaxation time, τ L, fits the results. The temperature dependence of the observed dynamics is interpreted.
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