Fast energy storage performance of CoFe2O4/CNTs hybrid aerogels for potassium ion battery

Abstract

We report CoFe2O4 and carbon nanotubes hybrid aerogels as a novel anode material for potassium ion batteries (KIBs). The synthetic route take the advantage of marine biobased materials as the precursor and facilely produce large-scale production of hybrid CoFe2O4 and carbon nanotubes aerogels as the advanced anode. The hybrid aerogels deliver a remarkable capacity of 180 mAh g−1 with high stability over 200 cycles at a current density of 0.1 A g−1. The high rate charge/discharge reveals a relatively high capacity of 83 mAh g−1 even at the current density of 1.0 A g−1. In-situ XRD investigations reveal the phase evolution during charge/discharge, demonstrating the high stability of hybrid aerogels for the potassium intercalation/extraction. The high specific surface area and large numbers of mesopores with more active sites can benefit the effective transmission of electrons and K ions, leading to an improved specific capacity and cycle stability.