Fascinating inclusion of metal–organic complex moieties in dinuclear Mn(II) and Zn(II) compounds involving pyridinedicarboxylates and phenanthroline: Experimental and theoretical studies

Abstract

In the present study, we have reported the synthesis of two new dinuclear Mn(II) and Zn(II) metal–organic compounds, [Mn(2,5-PDC)(phen)2][Mn(phen)2(H2O)2]2Cl·10H2O (1) and [Zn(phen)3][Zn(2,6-PDC)2]·11.5H2O (2) (where, 2,5-PDC = 2,5-pyridinedicarboxylate, 2,6-PDC = 2,6-pyridinedicarboxylate, phen = 1,10-phenanthroline) at room temperature which have been characterized by elemental analysis, TGA, spectroscopic (FTIR, electronic) and single crystal X-ray diffraction techniques. A fascinating chloride-water supramolecular cluster in 1 and (H2O)13 H-bonded cluster in 2 along with π-stacked assemblies stabilize the solid state structures. The most interesting aspect of the crystal structure of 1 is the inclusion of complex cationic moieties within the infinite self-assembled chloride-water cluster. Similarly the inclusion of cationic complex moieties in compound 2 inside the supramolecular cavity formed by the anionic complex provides rigidity to the crystal structure. DFT calculations, molecular electrostatic potential (MEP) surface analysis, quantum theory of atoms-in-molecules (QTAIM) and the non-covalent index plot (NCI plot) analysis were performed to investigate the supramolecular assemblies of the compounds. The studies reveal that the antiparallel π-stacking interactions are energetically significant synthons for the assemblies. However, the assemblies in 2 have been dominated mostly by Columbic attraction of the cationic and anionic complex moieties.