Abstract
AbstractFar infrared matrix isolation spectroscopy of hydrogen cyanide establishes the presence of monomers, linear dimers, and linear multimers in solid Ar. Information is obtained concerning the motion of monomer molecules relative to the cage as well as the intermolecular vibrational behaviour of the dimer. – The comparison with similar studies in the mid IR reveals the high potential of the application of far IR spectroscopy of matrix‐isolated samples to the investigation of association phenomena and intermolecular interactions.
Published Version
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