Failures and success in the author's works on lack of conformity of the generalized valence-optical IR and Raman intensity theories with rotational modes

Abstract

After the successful paper IV: 2016 (1) “On the conformity of valence-optical IR and Raman intensity theories with the Mayants-Averbukh approach”, the author has reexamined the old three underlying papers, paper I: 1977 (2), paper II: 1981 (3) and paper III: 1984 (4). In paper I the author presented the correct appearance of the parameter matrix DnoGVO:ZOA, which represents the vibrational modes of the Generalized valence-optical (GVO) IR intensity theory expressed in the formalism of the Mayants-Averbukh IR intensity theory. Else, paper I was a failure. In paper II and paper III important equations were created to be called the main rotational GVO IR and Raman equations. There they were used by the author to solve the problems on lack on conformity of the GVO IR and Raman intensity theories with rotational modes. Only the valence-optical (VO) intensity theories were retained. In the present paper a new discovery has been made with the aid of these equations. They have been found to contain hidden precious gifts: the appearances of the parameter matrices DnoGVO:ZOAand FnoGVO:ZOA. However, both in the IR case (paper II) and in the Raman case (paper III), the author had made rather meaningless divisions of these main rotational GVO IR and Raman equations into irreducible parts. This resulted in unrevealed subsidiary equations and unresolved “unique” parameter interpretations. These are big flaws in paper II and paper III. In the present paper these flaws have been resolved.