Abstract

In order to identify the causes of a bursting incident that occurred on the inner pipe of a jacketed pipe in a tubular heat exchanger for synthesis of high pressure polyethylene, series of characterization analysis were conducted. Metallurgical structure and chemical composition of the pipe’s metal matrix were inspected by metallographic microscope (MM) and photoelectric direct reading spectrometer; scanning electron microscope (SEM) and energy dispersive spectroscope (EDS) were applied to observe the microscopic morphology and micro-area composition on the ruptured surface; compositions of the coolant, i.e. the circulating cooling water were examined by inductively coupled plasma-atomic emission spectrometry (ICP-AES), ion chromatography (IC) and Fourier transform infrared spectroscopy (FTIR). In addition to these, finite element analysis (FEA) was employed to study the erosive effect of on the pipe. Analysis results revealed that interaction between corrosion and erosion both led by scaling, was the main cause that accelerated its thinning and eventually resulted in its premature failure. Finally countermeasures and suggestions were proposed.

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