Factors contributing to elevated concentrations of PM2.5 during wintertime near Boise, Idaho

Abstract

Wintertime chemical composition of water–soluble particulate matter with aerodynamic diameter less than 2.5μm (PM2.5) was monitored in the Treasure Valley region near Boise, Idaho. Aerosol was sampled using a Particle Into Liquid Sampler (PILS) and subsequently analyzed using ion exchange chromatography and a total organic carbon analyzer. During the two–month sampling campaign, the region experienced varying meteorological regimes, with an extended atmospheric stagnation event towards the end of the study. For all of the weather regimes, water–soluble PM2.5 was dominated by organic material, but particulate nitrate showed the greatest variation over time. These variations in particulate nitrate concentration were found to be dependent on the time of day, nitrogen oxides (NOX) concentrations, and relative humidity. The increases in particulate nitrate did not correlate with an equivalent molar increase of ammonium concentration, ruling out solid ammonium nitrate formation as the dominant source. Instead, our analysis using an online aerosol thermodynamic model suggests that the condensation of gas phase nitric acid was possible within the meteorological conditions experienced during the study. In running this model, atmospheric chemical and physical parameters close to those observed during the study were used as model input. The simulation was run for three different scenarios, representing the different meteorological regimes experienced during the study. From the simulation particulate nitrate concentration was highest during cold and humid nights. Currently this region is in attainment with the National Ambient Air Quality Standards (NAAQS) for PM2.5; however, with the projected increase in population and economic growth, and the subsequent increase in NOX emissions, these episodic increases in particulate nitrate have the potential of pushing the area to non–attainment status.