Abstract

Biodiesel (fatty acid alkyl ester) has received attention as greener, renewable, alternative source of energy; and its utilization as diesel fuel is becoming an auspicious source of energy that can substitute the non-renewable petroleum products. It can make significant contributions in diminishing the emission of harmful gaseous due to combustion of conventional fuel sources and hence, it is helpful to overcome challenges associated with energy crisis coupled with environmental pollution, climate change and global warming. Biodiesel is a carbon-neutral fuel source, biodegradable, non-toxic and can be synthesized from locally available non-edible vegetable oils via base-catalyzed transesterification process. This study presents the insight of operational variables or factors that influence the processing and yield of biodiesel (fatty acid alkyl ester) through transesterification of non-edible vegetable oils. These operational variables include, the amount of free fatty acid (FFA) in the non-edible vegetable oils, moisture in the oils, the amount and types of alcohol used, the non-edible vegetable oil to alcohol molar ratio, time allowed for the reaction, intensity of mixing, temperature, types of catalyzed used, concentration of catalyst and purity of reactants. The considered variables for preparation of biodiesel should be optimized to achieve the maximum possible conversion of reactants and thereby provide the highest possible yield of biodiesel product at the minimum possible operational cost.

Highlights

  • The growth of demand in exploitation as well as usage of energy, the rise in oil price, the increase in fossil fuel consumption in industry and in transportation sectors, global warming due to the emissions of harmful gaseous into atmosphere, depletion of petroleum reserves, the increase in carbon dioxide (CO2) level due to combustion of conventional fossil fuels have exacerbated the regional and global environment [1]

  • A renewable energy source, is a fuel with chain fatty acid mono-alkyl esters synthesized from non-edible vegetable oils, waste cooking oil, microalgae and fats via transesterification of chemical reaction with appropriate alcohol and suitable catalysts [6,7,8,9]

  • The present study aims at providing the insight of factors affecting biodiesel synthesis from non-edible vegetable oil via base catalyzed transesterification mechanism

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Summary

Introduction

The growth of demand in exploitation as well as usage of energy, the rise in oil price, the increase in fossil fuel consumption in industry and in transportation sectors, global warming due to the emissions of harmful gaseous into atmosphere, depletion of petroleum reserves, the increase in carbon dioxide (CO2) level due to combustion of conventional fossil fuels have exacerbated the regional and global environment [1] These environmental issues induce the emergence of alternative, renewable, biodegradable and environmentally friendly energy sources like biofuels (i.e. biodiesel) for transportation substituting the limited petroleum reserves; and thereby mitigating climate change while ensuring the sustainable development. The present study aims at providing the insight of factors affecting biodiesel synthesis from non-edible vegetable oil via base catalyzed transesterification mechanism

The Transesterification Reaction Catalyzed by Base
Amount of FFA in the Oil
Oil Moisture Content
Type of Alcohol Employed and Oil to Alcohol Molar Ratio
Reaction Time
Intensity of Mixing
Reaction Temperature
Catalyst Type and Concentration
Findings
Conclusion
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