Facile synthesis, phase transition, optical switching and oxidation resistance properties of belt-like VO2(A) and VO2(M) with a rectangular cross section

Abstract

Belt-like VO2(A) with a rectangular cross section (VA-RCS) was successfully synthesized using V2O5, H2C2O4·2H2O and H2O as the starting materials by a facile hydrothermal approach. Some synthetic parameters, such as, the reaction time, reaction temperature and concentration of H2C2O4·2H2O, were systematically investigated to control the fabrication of belt-like VA-RCS. The formation mechanism of belt-like VA-RCS was proposed. Subsequently, belt-like VO2(M) with a rectangular cross section (VM-RCS) was prepared by the irreversible transformation of VA-RCS at 700°C for 2h under the inert atmosphere. The phase transition temperature (Tc) of VA-RCS and VM-RCS was evaluated by DSC test. The optical switching properties of VA-RCS and VM-RCS were studied by the variable-temperature infrared spectra, and it was found that the as-obtained VA-RCS and VM-RCS could be used as the optical switching materials. Furthermore, the oxidation resistance properties of VA-RCS and VM-RCS were investigated by TGA, indicating that they have good thermal stability and oxidation resistance below 400°C in air.