Abstract

A series of 11 1,1-dimethyl-3-aryl-thioureas were synthesised in good yields (70–92%) by reacting arylamines with S-aryl- N,N-dimethylthiocarbamate in DMSO in the presence of NaH at 90 °C. It is noteworthy that this method can also be used for arylamines containing a halogen atom at the ortho position.

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