Abstract

The selective synthesis of a series of new "ladderlike" one-dimensional organometallic-organic hybrid polymers is shown. The polymers are obtained from the reaction of the diphosphorus ligand complex [Cp2Mo2(CO)4(η(2)-P2)] with the copper salt [Cu(CH3CN)4]BF4 in the presence of flexible organic bipyridyl linkers in high selectivity. This unique behaviour is supported by DFT calculations.

Highlights

  • The selective synthesis of a series of new ‘‘ladderlike’’ onedimensional organometallic–organic hybrid polymers is shown

  • The polymers are obtained from the reaction of the diphosphorus ligand complex [Cp2Mo2(CO)4(g2-P2)] with the copper salt [Cu(CH3CN)4]BF4 in the presence of flexible organic bipyridyl linkers in high selectivity

  • Those reactions yielded selectively the novel one-dimensional organometallic–organic coordination polymers [5,6,7,8] (Scheme 1, Fig. 2), where, to the best of our knowledge, no general approach has yet been reported to synthesize selectively coordination polymers based on flexible organic linkers and organometallic nodes

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Summary

Introduction

The selective synthesis of a series of new ‘‘ladderlike’’ onedimensional organometallic–organic hybrid polymers is shown. The polymers are obtained from the reaction of the diphosphorus ligand complex [Cp2Mo2(CO)4(g2-P2)] with the copper salt [Cu(CH3CN)4]BF4 in the presence of flexible organic bipyridyl linkers in high selectivity.

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Conclusion
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