Abstract
Capacitive deionization (CDI) is an effective desalination technique offering an appropriate route to obtain clean water. In order to obtain excellent CDI performance, a rationally designed structure of electrode materials has been an urgent need for CDI application. In this work, a novel graphene sponge (GS) was proposed as CDI electrode for the first time. The GS was fabricated via directly freeze-drying graphene oxide solution followed by annealing in nitrogen atmosphere. The morphology, structure and electrochemical performance of GS were characterized by scanning electron microscopy, Raman spectroscopy, nitrogen adsorption-desorption, X-ray photoelectron spectroscopy, cyclic voltammetry and electrochemical impedance spectroscopy. The electrosorption performance of GS in NaCl solution was studied and compared with pristine graphene (PG). The results show that due to the unique 3D interconnected porous structure, large accessible surface area and low charge transfer resistance, GS electrode exhibits an ultrahigh electrosorption capacity of 14.9 mg g−1 when the initial NaCl concentration is ~500 mg L−1, which is about 3.2 times of that of PG (4.64 mg g−1), and to our knowledge, it should be the highest value reported for graphene electrodes in similar experimental conditions by now. These results indicate that GS should be a promising candidate for CDI electrode.
Highlights
Facile synthesis of novel graphene sponge for high performance capacitive deionization Xingtao Xu1, Likun Pan[1], Yong Liu[1], Ting Lu1, Zhuo Sun1 & Daniel H
The results show that due to the unique 3D interconnected porous structure, large accessible surface area and low charge transfer resistance, graphene sponge (GS) electrode exhibits an ultrahigh electrosorption capacity of 14.9 mg g21 when the initial NaCl concentration is,500 mg L21, which is about 3.2 times of that of pristine graphene (PG) (4.64 mg g21), and to our knowledge, it should be the highest value reported for graphene electrodes in similar experimental conditions
Capacitive deionization (CDI) electrodes are typically made of porous carbon materials, such as activated carbon (AC)[12,13,14], carbon nanotubes (CNTs)[15,16,17,18,19], carbon aerogel (CA)[20,21,22], carbon fibers (CNFs)[23,24,25], mesoporous carbon (MC)[26,27] and others
Summary
Facile synthesis of novel graphene sponge for high performance capacitive deionization Xingtao Xu1, Likun Pan[1], Yong Liu[1], Ting Lu1, Zhuo Sun1 & Daniel H. CDI electrodes are typically made of porous carbon materials, such as activated carbon (AC)[12,13,14], carbon nanotubes (CNTs)[15,16,17,18,19], carbon aerogel (CA)[20,21,22], carbon fibers (CNFs)[23,24,25], mesoporous carbon (MC)[26,27] and others Among these carbon species, graphene with a flexible planar structure (ultrathin layer), high specific surface area (theoretically ,2600 m2 g21) and superior electron mobility (theoretically ,2.5 3 105 cm[2] V21 s21 at room temperature), has been theoretically and experimentally demonstrated to possess superior CDI performance[28,29,30,31,32,33,34]. When used as CDI electrode, GS exhibits an ultrahigh electrosorption capacity of 14.9 mg g21 in NaCl solution with an initial concentration of ,500 mg L21
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