Facile synthesis of mesoporous polymeric carbon nitride nanosheets anchored by Pt with ultralow loading for high-efficiency photocatalytic H2 evolution.

Abstract

The facile fabrication of low-cost photocatalysts with enhanced activity and high atomic utilization is becoming increasingly necessary for solar energy usage and/or conversion. In this work, a series of mesoporous carbon nitride nanosheets with an enlarged specific surface area was synthesized via an inorganic acid-assisted exfoliation method without any soft or hard templates. An ultralow loading of downsized noble metal Pt was anchored on these porous nanosheets, exhibiting enhanced photocatalytic activity. The formation of mesoporous nanosheets in carbon nitride was expected to boost the mass transfer and shorten the charge carrier transfer route during the photocatalytic reaction. The characterization of samples revealed that the enhanced conductivity and photocurrent of the carbon nitride nanosheets also contributed to the enhanced H2 evolution activity. The maximum H2 production rates of 172.92 μmol h-1 and 321 μmol h-1 were achieved over the nanosheets derived from melamine and urea under visible light irradiation, which are 10.92- and 2.22-fold that of the corresponding bulk carbon nitride, respectively. This exfoliation method was demonstrated to be an efficient and universal method for the preparation of carbon nitride nanosheets with a mesoporous structure and high atom utilization of the co-catalyst for H2 evolution from water.