Abstract
The first examples of quantitative migratory insertion of allene, 1,1-dimethylallene (DMA) and tetramethylallene (TMA) into alkyl and acyl palladium complexes containing bidentate and terdentate nitrogen ligands are presented; very stable palladium η3-allyl compounds containing 2,2′-bipyridine and 2-(2-{[(6′-methyl-2-pyridyl)methylene]amino}ethyl)-pyridine and an exceptional η1-allyl palladium complex containing terpy have been obtained.
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