Facile synthesis of carbon dots via pyrolysis and their application in photocatalytic degradation of rhodamine B (RhB).

Abstract

CarbonQuantum dot(CQDs) is one of the newest materials in carbon-based nanomaterials. It is pertinent to study the synthesis and the application of these carbon dots. Here we have studied the effect of precursor on the optical, morphological, and photocatalytic properties of CQDs. We have synthesized CQDs using pyrolysis method using the precursors citric acid, urea, polyethyleneimine. We have synthesized two samples: CQD-S1; synthesized using urea and polyethyleneimine, and CQD-S2; synthesized using citric acid and polyethyleneimine. In optical properties study two distinct peaks have been obtained at 243nm and 345nm for CQD-S1, and at 265nm and 335nm for CQD-S2. In fluorescence study, the maximum emission was found atexcitation wavelength of 340nm for CQD-S1 and atexcitation wavelength of 350nm for CQD-S2. In morphological studies, Transmission Electron Microscope (TEM) revealed particle size of sample CQD-S1 and CQD-S2 were 1.91nm and 1.61nm, respectively. EDX confirmed the elemental composition in both samples. The rhodamine B (RhB) dye degradation percentages in dark and under visible and UV light were found to 6, 13, and 98.4% respectively for CQD-S1. Similarly, dye degradation for CQD-S2 were 7, 11, and 99.63%, respectively. Effective degradation of photocatalysis performed under UV-light within 100min using mineralization process.