Facile synthesis of amphiphilic peach gum polysaccharide as a robust host for efficient encapsulation of methylene blue and methyl orange dyes from water

Abstract

Despite impressive progress of macromolecular encapsulation technique based on hyperbranched polymer (HP), the use of natural HP for guest encapsulation has rarely been reported. Herein, we present the simple synthesis of amphiphilic PGP-DC from natural peach gum polysaccharide (PGP) and demonstrate that the PGP-DC can be utilized as a robust host for encapsulation of dye molecules from water. The influences of initial dye concentration, dosage of PGP-DC, pH, ionic strength, and encapsulation mode on the encapsulation were systematically studied. The PGP-DC simultaneously exhibited fast encapsulation rate and superior encapsulation capability. Under optimal conditions, the encapsulation capacity of PGP-DC towards methylene blue (MB) (1 mM) can reach as high as 182.67 mg/g, which compares favorably to other separation techniques. Moreover, the MB-encapsulated PGP-DC could be well regenerated in acidic solution. Based on its simple synthetic process, excellent encapsulation performance and fine reusability, the PGP-DC holds great promise for using as a host for practical encapsulation applications.