Abstract

CoFe2O4 nanostructures were prepared by a facile co-precipitation route using polyvinyl alcohol (PVA) and sodium dodecyl sulphate (SDS) as capping agents. The effects of PVA and SDS concentration on the structural, optical behaviour and photocatalytic response of the prepared CoFe2O4 nanostructures were studied. XRD studies showed cubic spinel structure of CoFe2O4 nanostructures. The crystallite size of CoFe2O4 nanostructures was found to vary from 13 to 19.2 nm with change in PVA and SDS concentration, while the optical band gap varied from 2.2 to 2.31 eV. CoFe2O4 nanostructures prepared using optimal SDS concentration exhibited enhanced photocatalytic performance and efficiently degraded methylene blue in only 20 min of solar illumination. In situ scavenger studies confirmed the photoexcited electrons to be the major active species responsible for the strong photocatalytic performance of CoFe2O4 nanostructures. The observed strong photocatalytic response of nanostructured CoFe2O4 photocatalysts and their simpler magnetic separation capability make them promising for photocatalytic water purification applications.

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