Abstract
An in - situ reduction method is adopted to incorporate MnO 2 nanoparticles into mesochannels of silica thin films by using KMnO 4 as the oxidizing agent and manganese precursor. As the reduction time in KMnO 4 solution increases, the ordered mesostructure collapses, and the loaded MnO 2 nanoparticles become bigger in size, resulting in a narrower band gap. Z scan measurement demonstrates a large third-order nonlinear susceptibility of the composite films under the picosecond Nd:YAG laser excitation. A sign reversion of the third-order nonlinear refractive index coefficient in the sample with longer reduction time is also observed, which can be attributed to the variation in the band gap energy.
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