Facile synthesis and electronic structure optimization of sub-nanometer palladium clusters for efficient direct synthesis of H2O2

Abstract

A sub-nanometer Pd/ZDC catalyst for efficient H2O2 direct synthesis has been successfully prepared by regulating the pore size and nitrogen configuration, achieving a remarkable H2O2 selectivity of 81.6% and productivity of 3323 mmol gPd−1 h−1.