Abstract
Abstract meso-Tetrakis(4′-diethoxyphosphorylphenyl)porphyrin (H2TPhPP) was synthesized via modified Lindsey method with higher yield (50%) as compared to reported methods. H2TPhPP exhibited 120–140 mV anodic shifts in first ring redox potentials as compared to H2TPP. Similarly, anodic shifts of MTPhPP (M = Ni(II), Cu(II), and Zn(II)) were 70–210 mV in first ring oxidation potentials and 80–120 mV in first ring reduction potentials, as compared to corresponding MTPPs due to the strong electron-withdrawing nature of diethoxyphosphoryl substituents.
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