Abstract
AbstractIn this work, three different tochilinite‐like materials have been obtained by sophisticated synthetic methods that allow to control the distribution of iron ions. The purity of the samples was confirmed by powder X‐ray diffraction. From elemental analysis and Mössbauer spectroscopy data, detailed compositions could be determined: T1) Fe0.76S*0.86 [Fe2+0.01Fe3+0.56Mg2+0.43(OH)2.01]; T2) Fe0.89S*0.85 [Fe2+0.55Fe3+0.11Al3+0.33(OH)1.84(O)0.16]; T3) Fe0.71S*0.79 [Fe2+0.25Fe3+0.73Mg2+0.01Al3+0.01(OH)1.98(O)0.02]. These compositions fit to typical compositions of tochilinite in regard of the amount of iron vacancies and the volume ratio of the hydroxide layers to the sulfide layers. Besides hydroxide ions, oxide ions are also present in the hydroxide layers as a result of surface oxidation after the synthesis due to the high reactivity of the particles. TEM and SEM investigations show that the obtained powders consist mainly of thin sheets accompanied by nanotubes with BET surface areas ranging between 20 m2/g and 40 m2/g. The thermal stability was investigated by TGA and DSC analysis and it depends significantly on the composition.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Zeitschrift für anorganische und allgemeine Chemie
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
