Facile purification of glass fiber powder by sedimentation for enhanced epoxy resin composites

Abstract

Glass fiber powder contains two distinct forms: crumb-shaped and rod-shaped glass fiber powder particles. The shape and size of the particles in glass fiber powder have a great influence on its application. In order to separate rod-shaped glass fiber, the effects of different dispersants, such as SHMP, NaOL, and Na2SiO3 on them were investigated by settling experiments. Zeta potential, X-ray photoelectron spectroscopy (XPS), optical microscope, and other methods were used to analyze the adsorption behavior and settling mechanism. Three-point bending experiment and dynamic mechanical analysis (DMA) were used to evaluate the performance of epoxy resin composites reinforced with the raw glass fiber powder and the rod-shaped glass fiber powder. The results show that SHMP can effectively separate crumb-shaped glass fiber powder and rod-shaped glass fiber powder, leading to a notable increase in sedimentation recovery difference, up to Δ=51.08%. A preferential sedimentation separation mechanism is proposed to elucidate the settling mechanism. When the content of glass fiber powder and rod-shaped glass fiber is 5%, the glass transition temperature shifts significantly towards higher values, leading to the optimum comprehensive mechanical properties of the composites. Compared with the original epoxy resin, the flexural strength increased by 10.38% to 95.18 MPa and by 20.11% to 103.57 MPa. Similarly, the storage modulus increased by 14.14% to 2083 MPa and by 21.64% to 2220 MPa.