Facile protection of carbonyl compounds as oxathiolanes and transoxathioacetalization of oxyacetals promoted by iron(III) trifluoroacetate or trifluoromethanesulfonate as chemoselective and recyclable catalysts

Hadi Adibi,Hadi Jafari

doi:10.1016/j.jfluchem.2007.04.002

Facile protection of carbonyl compounds as oxathiolanes and transoxathioacetalization of oxyacetals promoted by iron(III) trifluoroacetate or trifluoromethanesulfonate as chemoselective and recyclable catalysts

Hadi Adibi, Hadi Jafari

https://doi.org/10.1016/j.jfluchem.2007.04.002

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Journal: Journal of Fluorine Chemistry	Publication Date: Apr 6, 2007
Citations: 13

Affiliation: Kermanshah University of Medical Sciences, Razi University, Islamic Azad University, Tehran

#CF 3CO #CF 3SO + Show 8 more

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Abstract

Oxathioacetalization of carbonyl compounds and transoxathioacetalization of O, O-acetals/ketals are reported under nearly neutral conditions promoted by iron(III) trifluoroacetate [Fe(CF 3CO 2) 3] or trifluoromethanesulfonate [Fe(CF 3SO 3) 3] as recyclable and highly efficient Lewis acid catalysts.

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