Facile production of smart superhydrophobic nanocomposite for wood coating towards long-lasting glow-in-the-dark photoluminescence.

Abstract

A smart photoluminescent nanocomposite surface coating was prepared for simple industrial production of long-persisting phosphorescence and superhydrophobic wood. The photoluminescent nanocomposite coatings were capable of continuing to emit light in the dark for prolonged time periods that could reach 1.5 h. Lanthanide-doped aluminium strontium oxide (LASO) nanoparticles at different ratios were immobilized in polystyrene (PS) and developed as a nanocomposite coating for wood substrates. To produce transparency in the prepared nanocomposite coating, LASO was efficiently dispersed in the form of nanoscaled particles to ensure homogeneous dispersion without agglomeration in the PS matrix. The coated wood showed an absorption band at 374 nm and two emission bands at 434 nm and 518 nm. The luminescence spectra showed both long-persisting phosphorescence as well as photochromic fluorescence relying on the LASO ratio. The improved superhydrophobicity and resistance to scratching of the coated wood could be attributed to the LASO NPs incorporated in the polystyrene matrix. Compared with the uncoated wood substrate, the coated LASO-PS nanocomposite film also displayed photostability and high durability. The current study demonstrated the potential high-scale manufacturing of smart wood for some applications such as safety directional signs in buildings, household products, and smart windows.