Facile preparation of ZIF-8/ZIF-67-derived biomass carbon composites for highly efficient electromagnetic wave absorption

Abstract

Biomass absorbing materials have received increasing attention for electromagnetic wave (EMW) absorption field absorbing materials due to its low density and high dielectric loss. However, the biomass EMW absorbing materials often suffer from the insufficient magnetic loss and impedance matching. In this work, a facile ZIF-8/ZIF-67-derived biomass composites (CoZnO@BPC) was prepared for high-performance EMW absorption based on multi-component micro, nano structures metal particles and xanthoce sorbifolia bunge shells-derived biomass porous carbon (BPC). The dielectric loss and/or magnetic loss abilities of CoZnO@BPC composites were adjusted by changing the mass ratio of Zn2+ to Co2+ ions. Under the filled amount of 20 wt%, CoZnO@BPC exhibited excellent EMW absorption with the minimum reflection loss (RL) at 15.84 GHz is -50.2 dB, and the matching thickness is only 1.7 mm. By adjusting the ZIFs mass ratio, the effective absorption bandwidth (EAB) can be up to 5.92 GHz (from 12.08 GHz to 18 GHz), and the matching thickness is only 1.9 mm. The results provide a new insight for the economical and efficient preparation of lightweight and advanced microwave absorbing materials.