Facile preparation of robust dual MgO-loaded carbon foam as an efficient adsorbent for malachite green removal

Abstract

This study developed a facile approach for the fabrication of dual MgO-loaded carbon foam (DMCF) via carbonization of a cured MgO/cyanate ester resin mixture, which underwent self-foaming of the resin followed by the carbothermal reduction of MgO. The features of the prepared DMCF prepared were characterized by FESEM, TEM, XRD, FTIR, XPS and so on, and the effects of adsorption conditions, adsorption isotherms, kinetics, and thermodynamics on malachite green (MG) removal using the DMCF as adsorbents were investigated through batch adsorption experiments. Results demonstrate that the DMCF possesses a unique dual loading of MgO particles which are not only loaded onto its foam walls but also filled within the walls with a graphene-wrapped core-shell structure. The experimental maximum adsorption capacity of MG reaches up to 1874.18 mg/g with a partition coefficient of 10.87 mg/g/μM. The adsorption process can be better described with Langmuir, pseudo-second-order, and intraparticle diffusion models. Moreover, the DMCF exhibits a removal percentage of 84.85% after five reuses, indicating that it is an efficient and promising adsorbent for MG adsorption.