Facile Preparation of Porous Rod-like Cu x Co3-x O4/C Composites via Bimetal-Organic Framework Derivation as Superior Anodes for Lithium-Ion Batteries.

Abstract

To meet growing demand of energy, lithium-ion batteries (LIBs) are under enormous attention. The development of well-designed ternary transition metal oxides with high capacity and high stability is important and challengeable for using as electrode materials for LIBs. Herein, a new and highly reversible carbon-coated Cu-Co bimetal oxide composite material (CuxCo3–xO4/C) with a one-dimensional (1D) porous rod-like structure was prepared through a bimetal–organic framework (BMOF) template strategy followed by a morphology-inherited annealing treatment. During the annealing process, carbon derived from organic frameworks in situ fully covered the synthesized bimetal oxide nanoparticles, and a large number of porous spaces were generated in the MOF-derived final samples, thus ensuring high electrical conductivity and fast ion diffusion. Benefiting from the synergetic effect of bimetals, the unique 1D porous structure, and conductive carbon network, the as-synthesized CuxCo3–xO4/C delivers a high capacity retention up to 92.4% after 100 cycles, with a high reversible capacity still maintained at 900 mA h g–1, indicating an excellent cycling stability. Also, a good rate performance is demonstrated. These outstanding electrochemical properties show us a concept of synthesis of MOF-derived bimetal oxides combining both advantages of carbon incorporation and porous structure for progressive lithium-ion batteries.