Abstract

Novel CuO hybrid nanostructures composed of one-dimensional (ID) porous carbon nanofibers and two-dimensional (2D) graphene nanosheets have been fabricated with the help of electrospinning technique, which is denoted as CuO@PCNF/GN. The microstructure and morphology of the CuO@PCNF/GN were investigated by X-ray diffraction and transmission electron microscopy. The electrochemical performances of the as-prepared materials as a novel bind-free anode for lithium ion battery (LIB) were investigated. The CuO@PCNF/GN electrode exhibited high discharge capacity of 665 mAh g−1 after 60 cycles at the current density of 100 mA g−1. Even at 800 mA g−1, the discharge capacity of the anode could still maintained at 443 mAh g−1. The excellent electrochemical properties of CuO are greatly related to the unique 3D interconnected structure of continuous PCNF and GN, which enables efficient electron/ion transport and migrate the volume change of active CuO materials.

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