Facile one-step electrochemical deposition of copper nanoparticles and reduced graphene oxide as nonenzymatic hydrogen peroxide sensor

Abstract

For several decades, hydrogen peroxide has exhibited to be an extremely significant analyte as an intermediate in several biological devices as well as in many industrial systems. A straightforward and novel one-step technique was employed to develop a sensitive non-enzymatic hydrogen peroxide (H2O2) sensor by simultaneous electrodeposition of copper nanoparticles (CuNPs) and reduced graphene oxide (rGO). The electroreduction performance of the CuNPs-rGO for hydrogen peroxide detection was studied by cyclic voltammetry (CV) and chronoamperometry (AMP) methods The CuNPs-rGO showed a synergistic effect of reduced graphene oxide and copper nanoparticles towards the electroreduction of hydrogen peroxide, indicating high reduction current. At detection potential of −0.2V, the CuNPs-rGO sensor demonstrated a wide linear range up to 18mM with a detection limit of 0.601 mM (S/N=3). Furthermore, with addition of hydrogen peroxide, the sensor responded very quickly (<3s). The CuNPs-rGO presents high selectivity, sensitivity, stability and fast amperometric sensing towards hydrogen peroxide which makes it favorable for the development of non-enzymatic hydrogen peroxide sensor.